Conversationally, i agree that ex-wife seems much more common that former wife. In writing, though, the use of former doesn't seem so rare. Here's an interesting ngram.

Former LSU QBs Ryan Perriloux and Josh Booty to Compete on Reality TV Show!

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Former LSU QBs Ryan Perriloux and Josh Booty to Compete on Reality TV Show!
Former LSU QBs Ryan Perriloux and Josh Booty to Compete on Reality TV Show!
Former LSU QBs Ryan Perriloux and Josh Booty to Compete on Reality TV Show!
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